Reactions of 9,10-dioxatricyclo[6.2.2.0(1,6)]dodeca-3,11-dien-6-yl hydroperoxide: synthesis of oxygenated naphthalene derivatives

Kishali N., KARA Y.

TETRAHEDRON, cilt.64, sa.34, ss.7956-7959, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 64 Sayı: 34
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.tet.2008.06.020
  • Dergi Adı: TETRAHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.7956-7959
  • Atatürk Üniversitesi Adresli: Evet

Özet

We synthesized 9,10-dioxatricyclo[6.2.2.0(1,6)]dodeca-3,11-dien-6-yl hydroperoxide (7) and investigated for the first time its further chemical transformation with dimethylsulfide, NEt3, PPh3, and Co-TPP, respectively. A variety of stereospecifically oxygenated compounds were obtained from these reactions containing different functional groups such as alcohols, ketone, and epoxides. (C) 2008 Published by Elsevier Ltd.