Optimization and modeling of boric acid extraction from colemanite in water saturated with carbon dioxide and sulphur dioxide gases


Ekinci Z., Sayan E., Bese A. V., Ata O. N.

International Journal of Mineral Processing, cilt.82, sa.4, ss.187-194, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 82 Sayı: 4
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1016/j.minpro.2006.10.007
  • Dergi Adı: International Journal of Mineral Processing
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.187-194
  • Anahtar Kelimeler: colemanite, boric acid, carbon dioxide, sulphur dioxide, statistical modeling, optimization, AMMONIUM-CHLORIDE SOLUTION, DISSOLUTION KINETICS, RED MUD, ULEXITE, TIO2
  • Atatürk Üniversitesi Adresli: Evet

Özet

In this study, the boric acid extraction from colemanite ore in aqueous media saturated by CO2 and SO2 gases was studied and the effects of relevant parameters, namely; reaction temperature, solid-to-liquid ratio, mean particle size, stirring speed and reaction time have been investigated on the boric acid extraction from colemanite ore by using the fractional factorial design and central composite design methods. The chosen experimental parameter levels were as follows: reaction temperature, 11.4-58.6 °C; solid-to-liquid ratio, 0.0685-0.1315 g/mL; mean particle size, 0.2835-3 mm; stirring speed, 107-893 rpm; reaction time, 7.125-22.875 min. A model has been developed between the boric acid extraction efficiency from colemanite ore and relevant parameters by means of variance analysis by using the matlab computer software and the obtained model was used to determine optimum conditions. The optimum conditions were found to be as follows: reaction temperature, 41 °C; solid-to-liquid ratio, 0.0685 g/mL; mean particle size, 0.2835 mm; stirring speed, 266 rpm; reaction time, 7 min. The calculated boric acid extraction efficiency from colemanite ore was approximately 99.9% under the optimum conditions. © 2006 Elsevier B.V. All rights reserved.