Unusual chlorination during an epoxidation reaction of an etheno-cyclopropa[b]naphthalene derivative

ULKU D., TAHIR M., Menzek A., BALCI M.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.51, ss.2714-2715, 1995 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 51
  • Basım Tarihi: 1995
  • Doi Numarası: 10.1107/s0108270195009383
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.2714-2715
  • Atatürk Üniversitesi Adresli: Evet

Özet

The structure of (1 alpha,1a alpha,2 beta,7a alpha,8R,9R)-8,9-dichloro-1a,2,7,7a-tetrahydro-2,7-ethano-1H-cyclopropa[b]napthalene-1-carbonitrile, C14H11Cl2N, consists of two nonplanar six-membered carbon rings (constituting a [2.2.2] bicyclic system), one of which shares two C atoms with a benzene ring and has two Cl substituents; the other is fused to a cyclopropane ring carrying a C=N substituent. The two Cl atoms of the -C-C(Cl)-C(Cl)-C- bridging system have an anti arrangement with respect to the plane of the four C atoms.