Metal- and Base-Free Combinatorial Reaction for C-Acylation of 1,3-Diketo Compounds in Vegetable Oil: The Effect of Natural Oil

Menges N., ŞAHİN E.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, cilt.2, sa.2, ss.226-230, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 2 Sayı: 2
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1021/sc400281h
  • Dergi Adı: ACS SUSTAINABLE CHEMISTRY & ENGINEERING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.226-230
  • Atatürk Üniversitesi Adresli: Evet

Özet

C-acylation of 1,3-diketo compounds has been done successfully employing 1,3 diketo compounds, oxalyl chloride, and phenol derivatives through metal, base, and toxic solvent-free protocol. Dioxinone ring-bearing 1,3,3' tricarbonyl moiety was also obtained in the same conditions using salicyl aldehyde. All reactions were carried out in vegetable oil.