A simple route for the synthesis of 3,3,3 ',3 '-tetramethyl-2,3,3 ',4 '-tetrahydro-1H,1 ' H-[4,9 '-bixanthene]-1,1 '(2 ' H,9 ' H)-dione and its derivatives catalyzed by Mn2+ and other transition metal cations


Pesyan N. N., Golsanamloo V., Ganbari S., ŞAHİN E.

TETRAHEDRON LETTERS, cilt.53, sa.32, ss.4096-4099, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 53 Sayı: 32
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1016/j.tetlet.2012.05.116
  • Dergi Adı: TETRAHEDRON LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.4096-4099
  • Atatürk Üniversitesi Adresli: Evet

Özet

A simple and efficient unusual coupling reaction of 9-(2-hydroxy-4,4-dimethy1-6-oxocyclohex-1-en-1yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-l-one and its derivatives was accomplished in the presence of Mn2+, Cu2+, Cd2+, Hg2+, Fe-3, or La3+. The structure elucidation was accomplished by IR, H-1 NMR, C-13 NMR, X-ray crystallography, UV-Visible and elemental analysis. A reaction mechanism is proposed. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.