Black phosphorus as a metal-free, visible-light-active heterogeneous photoredox catalyst for the direct C-H arylation of heteroarenes

Kalay, Erbay; Küçükkeçeci, Hüseyin; KILIÇ, Haydar; Metin, Önder

doi:10.1039/d0cc01874k

Black phosphorus as a metal-free, visible-light-active heterogeneous photoredox catalyst for the direct C-H arylation of heteroarenes

Kalay E., Küçükkeçeci H., KILIÇ H., Metin Ö.

Chemical Communications, vol.56, no.44, pp.5901-5904, 2020 (SCI-Expanded, Scopus)

Publication Type: Article / Article
Volume: 56 Issue: 44
Publication Date: 2020
Doi Number: 10.1039/d0cc01874k
Journal Name: Chemical Communications
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Communication Abstracts, EMBASE, MEDLINE, DIALNET
Page Numbers: pp.5901-5904
Ataturk University Affiliated: Yes

Abstract

Black phosphorus (BP) is for the first time employed as a metal-free, heterogeneous photoredox catalyst for the direct C-H arylation of heteroarenes with aryl diazonium salts. The arylated heteroarenes are obtained in moderate to good yields under visible-light illumination, and the protocol is shown to be applicable for the scale-up synthesis.