Black phosphorus as a metal-free, visible-light-active heterogeneous photoredox catalyst for the direct C-H arylation of heteroarenes


Kalay E., Küçükkeçeci H., KILIÇ H., Metin Ö.

Chemical Communications, vol.56, no.44, pp.5901-5904, 2020 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 56 Issue: 44
  • Publication Date: 2020
  • Doi Number: 10.1039/d0cc01874k
  • Journal Name: Chemical Communications
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Communication Abstracts, EMBASE, MEDLINE, DIALNET
  • Page Numbers: pp.5901-5904
  • Ataturk University Affiliated: Yes

Abstract

Black phosphorus (BP) is for the first time employed as a metal-free, heterogeneous photoredox catalyst for the direct C-H arylation of heteroarenes with aryl diazonium salts. The arylated heteroarenes are obtained in moderate to good yields under visible-light illumination, and the protocol is shown to be applicable for the scale-up synthesis.