Black phosphorus as a metal-free, visible-light-active heterogeneous photoredox catalyst for the direct C-H arylation of heteroarenes

Kalay E., Küçükkeçeci H., KILIÇ H., Metin Ö.

Chemical Communications, cilt.56, sa.44, ss.5901-5904, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 56 Sayı: 44
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1039/d0cc01874k
  • Dergi Adı: Chemical Communications
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Communication Abstracts, EMBASE, MEDLINE, DIALNET
  • Sayfa Sayıları: ss.5901-5904
  • Atatürk Üniversitesi Adresli: Evet

Özet

Black phosphorus (BP) is for the first time employed as a metal-free, heterogeneous photoredox catalyst for the direct C-H arylation of heteroarenes with aryl diazonium salts. The arylated heteroarenes are obtained in moderate to good yields under visible-light illumination, and the protocol is shown to be applicable for the scale-up synthesis.