Investigation of applicability of the various adsorption models of methylene blue adsorption onto lignite/water interface

Karaca S., Gurses A., Bayrak R.

ENERGY CONVERSION AND MANAGEMENT, cilt.46, sa.1, ss.33-46, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 46 Sayı: 1
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1016/j.enconman.2004.02.008
  • Dergi Adı: ENERGY CONVERSION AND MANAGEMENT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.33-46
  • Anahtar Kelimeler: adsorption isotherms, lignite, pyrolysis, functional groups, cationic dye, ACTIVATED CARBONS, AQUEOUS-SOLUTION, SURFACE-AREA, COAL, ADSORBENTS, REMOVAL, DYE
  • Atatürk Üniversitesi Adresli: Evet

Özet

Methylene blue adsorption isotherms for raw and pyrolysed coal samples were determined at 20 degreesC. The raw coal sample showed the highest adsorption capacity. It was observed that adsorption capacity generally decreased with increasing pyrolysis temperature. The sample pyrolysed at 700 degreesC exhibited the lowest adsorption capacity. The experimental data obtained were applied to the Freundlich, Langmuir, BET, Halsey, Harkins-Jura, Smith and Henderson isotherm equations to test the fitness of these equations to raw and pyrolysed coal samples. By considering the experimental results and adsorption models applied in this study, it can be concluded that adsorption of methylene blue occurs through physical interactions, and the lignite sample has a mesoporous structure. (C) 2004 Elsevier Ltd. All rights reserved.