Copy For Citation
ATILGAN A., TANRIVERDİ EÇİK E., GULİYEV R., UYAR B., ERBAS CAKMAK S., AKKAYA E. U.
Angewandte Chemie-International Edition, vol.53, pp.10678-10681, 2014 (SCI-Expanded)
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Publication Type:
Article / Article
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Volume:
53
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Publication Date:
2014
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Doi Number:
10.1002/anie.201405462
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Journal Name:
Angewandte Chemie-International Edition
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Journal Indexes:
Science Citation Index Expanded (SCI-EXPANDED), Scopus
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Page Numbers:
pp.10678-10681
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Keywords:
caged compounds, photochemistry, photosensitizers, singlet oxygen, zinc, PHOTOREMOVABLE PROTECTING GROUPS, UP-CONVERSION NANOPARTICLES, REACTION-MECHANISMS, ZINC, CHEMISTRY, NEUROBIOLOGY, CALCIUM, CANCER, ZN2+
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Ataturk University Affiliated:
No
Abstract
A ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal-ion affinity upon irradiation with low-energy red/near-IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions.