Nucleophilic substitution reactions of monofunctional nucleophilic reagents with cyclotriphosphazenes containing 2,2-dioxybiphenyl units

TANRIVERDİ EÇİK E., İBİŞOĞLU H., YENİLMEZ ÇİFTÇİ G., Demir G., Erdemir E., YÜKSEL F.

TURKISH JOURNAL OF CHEMISTRY, cilt.44, sa.1, ss.87-109, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44 Sayı: 1
  • Basım Tarihi: 2020
  • Doi Numarası: 10.3906/kim-1907-45
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.87-109
  • Atatürk Üniversitesi Adresli: Evet

Özet

The nucleophilic substitution reactions of mono- and bis-spiro-2,2'-dioxybiphenyl cyclotriphosphazenes (3 and 4) with cyclopropanemethylamine (5) and aniline (6) were performed in the presence of trimethylamine in THF. Five novel cyclopropanemethylamino- and anilino-substituted spiro-2,2'-dioxybiphenyl cyclotriphosphazene derivatives (7-11) were obtained from these reactions. The molecular structures of the new cyclotriphosphazene derivatives (7-11) were characterized by elemental analysis, MALDI-TOF MS, FT-IR, and NMR (P-31 and H-1) spectroscopies. The structure of the spiro-(2,2'-dioxybiphenyl)-bis-(anilino)-cyclotriphosphazene (11) was also determined by single-crystal X-ray crystallography.