One-Dimensional Ni(II) and Cu(II) Coordination Polymers Containing Syn-Syn Thiophene-2,5-dicarboxylate and Propane-1,3-diamine

YEŞİLEL O. Z., Ilker I., ŞAHİN E.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.21, sa.1, ss.103-109, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 21 Sayı: 1
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1007/s10904-010-9414-1
  • Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.103-109
  • Anahtar Kelimeler: Coordination polymers, Thiophene-2,5-dicarboxylate complexes, Thiophene-2,5-dicarboxylic acid, Propane-1,3-diamine, COPPER(II) COMPLEXES, CRYSTAL-STRUCTURES, ACID
  • Atatürk Üniversitesi Adresli: Evet

Özet

New thiophene-2,5-dicarboxylate complexes with the formula of [M(mu-tdc)(pen)(2)] (n) (M = Ni(II) (1) and Cu(II) (2), pen = propane-1,3-diamine, tdc = thiophene-2,5-dicarboxylate) have been synthesized and characterized by using thermal (TG/DTG, DTA and MS) analysis, IR and UV-Vis. spectroscopies, magnetic measurement and single crystal X-Ray diffraction techniques. The Ni(II) and Cu(II) ions are distorted octahedrally coordinated by two oxygen atoms of two bridging thiophene-2,5-dicarboxylate ligands and four nitrogen atoms of the trans-pen ligands. The polymeric chains are connected together by hydrogen bonds interactions, forming three-dimensional network.