Fluorescence properties of fluorenylidene bridged cyclotriphosphazenes bearing aryloxy groups

Çiftçi G. Y., Şenkuytu E., Incir E. S., Durmuş M., Yuksel F.

Polyhedron, cilt.102, ss.741-749, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 102
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.poly.2015.10.047
  • Dergi Adı: Polyhedron
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.741-749
  • Anahtar Kelimeler: Fluorenylidene, Cyclotriphosphazenes, Pyrene, Fluorescence properties, Chemosensor, LIGHT-EMITTING-DIODES, PHOTOPHYSICAL PROPERTIES, CRYSTAL-STRUCTURE, BIOLOGICAL-ACTIVITIES, CYCLIC PHOSPHAZENES, FLAME RETARDATION, DNA INTERACTIONS, FE3+ IONS, PYRENE, DERIVATIVES
  • Atatürk Üniversitesi Adresli: Hayır

Özet

The synthesis and characterization of the first series of aryloxy full-substituted fluorenylidene open chain and bridged cyclotriphosphazene derivatives (13-18) are reported in this study. The synthetic route utilized includes the reaction of penta-substituted cyclotriphosphazenes (5, 7, 9) with 4,4'-(9-fluorenylidene)diphenol (FDP) (11) and 4,4'-(9-fluorenylidene)dianiline (FDA) (12) to give bridged compounds (13, 15-17) and open chain compounds (14 and 18). The structural investigations of the compounds were verified by elemental analyses, mass spectrometry, UV-Vis, FT-IR, H-1 and P-31 NMR techniques, and X-ray crystallography (for 13 and 18). The fluorescence behavior of the studied cyclotriphosphazene derivatives were also examined in THF solution. Compound 16 showed a high emission among the studied compounds to investigate its metal sensing properties. This compound showed high selectivity for copper (Cu2+) and iron (Fe2+/Fe3+) ions in solution. (C) 2015 Elsevier Ltd. All rights reserved.