Oxidation of some alkoxy-cycloheptatriene derivatives: unusual formation of furan and furanoids from cycloheptatrienes


COSKUN A., GUNEY M., Dastan A., BALCI M.

TETRAHEDRON, cilt.63, sa.23, ss.4944-4950, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 63 Sayı: 23
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1016/j.tet.2007.03.145
  • Dergi Adı: TETRAHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.4944-4950
  • Atatürk Üniversitesi Adresli: Evet

Özet

The oxidation of some alkoxy tropone and tropone ketal derivatives with singlet oxygen and m-chloroperbenzoic acid was investigated. In most cases furan and furanoid derivatives were isolated. The structures of the formed products were determined by means of spectral data and the formation mechanism of these unusual products is discussed. (c) 2007 Elsevier Ltd. All rights reserved.