The new dispirobino and dispiroansa spermine derivatives of cyclotriphosphazenes

YENİLMEZ ÇİFTÇİ G., DAL H., TANRIVERDİ EÇİK E., HÖKELEK T., KILIÇ A., ŞENKUYTU E.

Polyhedron, cilt.29, sa.4, ss.1209-1218, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 29 Sayı: 4
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1016/j.poly.2009.12.022
  • Dergi Adı: Polyhedron
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1209-1218
  • Anahtar Kelimeler: Cyclotriphosphazenes, Spermine derivatives, Dispirobino, Dispiroansa, NMR, PHOSPHORUS-NITROGEN COMPOUNDS, NUCLEOPHILIC-SUBSTITUTION REACTIONS, ANSA DILEMMA, LINKED CYCLOPHOSPHAZENES, CHIRAL CONFIGURATIONS, PHOSPHAZENES, SPIRO, HEXACHLOROCYCLOTRIPHOSPHAZATRIENE, POLYAMINES, SPIRANSA
  • Atatürk Üniversitesi Adresli: Hayır

Özet

In this study, the crystal structures of the dispiroansa spermine derivatives of cyclotriphosphazene are characterised for the first time. The reaction of spiro-, gem-disubstituted cyclotriphosphazene derivatives, N3P3Cl4R2 [R = NHPh, (HN(CH2)(3)NH)(0.5), (OCH2C(CH3)(2)CH2O)(0.5)], (1-3), with spermine (4), in aprotic solvents such as CH2Cl2 results in a series of dispirobino spermine derivatives of cyclotriphosphazene (5a, 6a, 7), namely spermine bridged compounds. Whereas, in protic solvents such as CHCl3 give, dispiroansa derivatives (8-10) namely tetracyclic cyclotriphosphazene. The new series of dispirobino and dispiroansa spermine derivatives of cyclotriphosphazene (5a, 6a, 7-10) have been characterised by elemental analysis, mass spectrometry, X-ray (for 5a, 8,10) and H-1, P-31 NMR spectroscopies. (C) 2009 Elsevier Ltd. All rights reserved.