Chemosensor properties of 7-hydroxycoumarin substituted cyclotriphosphazenes

Yenilmez Ciftci G., Yilmaz S., Bayik N., Şenkuytu E., Kaya E. N., Durmuş M., ...Daha Fazla

Turkish Journal of Chemistry, cilt.44, sa.1, ss.64-73, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 44 Sayı: 1
  • Basım Tarihi: 2020
  • Doi Numarası: 10.3906/kim-1908-51
  • Dergi Adı: Turkish Journal of Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.64-73
  • Anahtar Kelimeler: Cyclotriphosphazene, coumarin, fluorescent chemosensor, aqueous media, ON FLUORESCENT CHEMOSENSOR, COUMARIN DERIVATIVES, FE3+ IONS, EMISSION, DYES, CYCLOPHOSPHAZENES
  • Atatürk Üniversitesi Adresli: Hayır

Özet

The newly synthesized cyclotriphosphazene cored coumarin chemosensors 5, 6, and 7 were successfully characterized by H-1 NMR, P-31 NMR, and MALDI-TOF mass spectrometry. Additionally, the photophysical and metal sensing properties of the targeted compounds were determined by fluorescence spectroscopy in the presence of various metals (Li+, Na+, K+, Cs+, Mg2+, Ca2+, Ba2+, Cr3+ Mn2+, Fe3+, Co2+, Al3+, Hg+, Cu2+, Zn2+, Ag+, and Cd2+). The fluorescence titration results showed that compounds 5, 6, and 7 could be employed as fluorescent chemosensors for Fe3+ ions with high sensitivity. The complex stoichiometry between final cyclotriphosphazene chemosensors and Fe3+ ions was also determined by Job's plots.