Transient formation of hydrogen tetraoxide from hydrogen peroxide with bis(trifluoroacetoxyiodo)benzene: A chemical generator of singlet oxygen for organic synthesis

CATIR M., Kilic H.

SYNLETT, sa.8, ss.1180-1182, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1055/s-2003-39889
  • Dergi Adı: SYNLETT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1180-1182
  • Anahtar Kelimeler: hypervalent iodine, hydrogen tetraoxide, singlet oxygen, oxygenation, peroxide
  • Atatürk Üniversitesi Adresli: Evet

Özet

Decomposition of hydrogen tetraoxide, produced by the reaction of hydrogen peroxide with bis(trifluoroacetoxyiodo) benzene, generates singlet molecular oxygen. Oxidation of typical organic substrates in an organic solvent through [4+2] cycloaddition and ene reactions have been carried out on a preparative scale.