Sequential rearrangement reactions of benzhomonorbornadiene derivatives: Synthesis of 7-vinylbenzonorbornadiene
HELVETICA CHIMICA ACTA, cilt.86, sa.2, ss.324-329, 2003 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 86 Sayı: 2
- Basım Tarihi: 2003
- Doi Numarası: 10.1002/hlca.200390034
- Dergi Adı: HELVETICA CHIMICA ACTA
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.324-329
- Atatürk Üniversitesi Adresli: Evet
Özet
The reaction of alcohol 12 with SOCl(2) gave chlorides 13 and 14, and the acetolysis of toluene-4-sulfonate 15 gave sequential rearrangement products 16, 17, and 18. In the reaction of 12, 13 is the major product of sequential rearrangements. Treatment of chloride 13 with t-BuOK gave 7-vinylbenzonorbornadiene 19.