Attempted synthesis of cyclopenta-1,2-diene and Wurtz-like condensation products in the reaction of 2,3-dibromocycloalkenes with zinc

CEYLAN M., Secen H., SUTBEYAZ Y.

JOURNAL OF CHEMICAL RESEARCH-S, sa.3, ss.70-71, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1039/a605543e
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.70-71
  • Atatürk Üniversitesi Adresli: Evet

Özet

Fluoride ion-promoted elimination of 2-bromo-3-trimethylsilylcyclopentene 5 and the reaction of five-, six- and seven-membered 2,3-dibromocycloalkenes with zinc gave Wurtz-like dimeric products instead of the expected cyclic allenes.