Attempted synthesis of cyclopenta-1,2-diene and Wurtz-like condensation products in the reaction of 2,3-dibromocycloalkenes with zinc

CEYLAN, Mustafa; Secen, Hasan; SUTBEYAZ, Yaşar

doi:10.1039/a605543e

Attempted synthesis of cyclopenta-1,2-diene and Wurtz-like condensation products in the reaction of 2,3-dibromocycloalkenes with zinc

CEYLAN M., Secen H., SUTBEYAZ Y.

JOURNAL OF CHEMICAL RESEARCH-S, sa.3, ss.70-71, 1997 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Basım Tarihi: 1997
Doi Numarası: 10.1039/a605543e
Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.70-71
Atatürk Üniversitesi Adresli: Evet

Özet

Fluoride ion-promoted elimination of 2-bromo-3-trimethylsilylcyclopentene 5 and the reaction of five-, six- and seven-membered 2,3-dibromocycloalkenes with zinc gave Wurtz-like dimeric products instead of the expected cyclic allenes.