Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins

Dagalan Z., Kocak R., DAŞTAN A., NİŞANCI B.

ORGANIC LETTERS, cilt.24, ss.8261-8264, 2022 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 24
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1021/acs.orglett.2c02627
  • Dergi Adı: ORGANIC LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, BIOSIS, Chemical Abstracts Core, Chimica, EMBASE, MEDLINE
  • Sayfa Sayıları: ss.8261-8264
  • Atatürk Üniversitesi Adresli: Evet

Özet

Herein, we report the first metal-free and molecular halogen reagent-free dihomohalogenation methodology by using Selectfluor as an oxidant and tetrabutylammonium bromide/ chloride salts as a halogen source. This effective strategy provides various fluorine-free halogenated products easily in quantitative yields from alkenes, alkynes, and natural products.