Development of a multiresidue method for the determination of multiclass pesticides in soil using GC

Park J., Mamun M. I. R., Choi J., HASSIBELNABY A. M. A., Assayed M. E., Choi W. J., ...Daha Fazla

BIOMEDICAL CHROMATOGRAPHY, cilt.24, sa.8, ss.893-901, 2010 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 24 Sayı: 8
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1002/bmc.1383
  • Dergi Adı: BIOMEDICAL CHROMATOGRAPHY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.893-901
  • Atatürk Üniversitesi Adresli: Hayır

Özet

The principal objective of the present study was to develop a multiresidue analytical method for 62 pesticides in a soil matrix. Soil samples were fortified with known quantities of pesticides at two different concentration levels (0.1 and 0.01 mu g/g) and the analytes were extracted via a liquid-solid extraction method. The pesticides were separated on an HP5 capillary column and were detected by gas chromatography coupled to an electron capture detector (GC-ECD). The method was validated, considering its good linearities (r(2) = 0.978-0.999), specificity and recovery characteristics. Recoveries were found between 70.3 and 113.4% for all pesticides except edifenphos (67.5%) and dichlobenil (69.5%) spiked at a 0.1 mu g/mL concentration level and 74.5-117% except ethalfluralin (63.3%) and dichlobenil (51.9%) spiked at a concentration of 0.01 mu g/mL. The developed method could be utilized as a simple and cost-effective method for the routine analysis of 62 pesticides in soil samples. Copyright (C) 2009 John Wiley & Sons, Ltd.