Bromination of benzonorbornadiene using a mixture of sodium bromide and sodium perborate at high temperatures

ŞENOCAK E., TAŞKESENLİGİL Y., TÜMER F.

TURKISH JOURNAL OF CHEMISTRY, cilt.26, sa.6, ss.939-945, 2002 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 26 Sayı: 6
  • Basım Tarihi: 2002
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.939-945
  • Atatürk Üniversitesi Adresli: Evet

Özet

Bromination of benzonorbornadiene (1) with sodium bromide in the presence of sodium perborate at room temperature gave only one product, the dibromide 2 produced via Wagner-Meerwein rearrangement. However, at high temperatures, bromination resulted predominantly in the formation of rearranged solvolytic products whose formation mechanisms are discussed.