Electrodeposited Nickel/Chromium(III) Oxide Nanostructure-Modified Pencil Graphite Electrode for Enhanced Electrocatalytic Hydrogen Evolution Reaction Activity

Korkmaz A. R., ÇEPNİ E., ÖZTÜRK DOĞAN H.

ENERGY & FUELS, cilt.35, sa.7, ss.6298-6304, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 35 Sayı: 7
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1021/acs.energyfuels.0c04413
  • Dergi Adı: ENERGY & FUELS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, PASCAL, Applied Science & Technology Source, Chemical Abstracts Core, Chimica, Compendex, Computer & Applied Sciences, Environment Index, Pollution Abstracts, DIALNET
  • Sayfa Sayıları: ss.6298-6304
  • Atatürk Üniversitesi Adresli: Evet

Özet

Electrolysis of water in acidic solutions is typically used in the production of electrocatalytic hydrogen. Herein, we proposed the electrochemical fabrication of the nickel/chromium(III) oxide (Ni/Cr2O3) nanostructure-modified pencil graphite electrode (PGE) for use as an electrode in hydrogen evolution reaction (HER) in 0.5 M sulfuric acid solution. The optimal combination of nanostructures was determined based on the highest electrocatalytic performance for HER. After determining the ideal experimental conditions for fabrication of Cr2O3, Ni nanoparticles were electrochemically deposited on the Cr2O3 nanostructure-modified PGE to prepare a low-cost electrocatalyst. The Ni/Cr2O3 nanostructure-modified PGEs were characterized through X-ray diffraction, X-ray photoelectron spectroscopy, energy-dispersive X-ray spectroscopy, and scanning electron microscopy. Linear sweep voltammetry, Tafel polarization curves, and electrochemical impedance spectroscopy were used for determining Fr reduction (Had formation) in acidic solution on modified and unmodified electrode surfaces. This study involves the fabrication of a low-cost, stable, and highly electroactive electrode material for hydrogen production in the electrolysis of water.