Reductions of Benzene Derivatives Whose Benzylic Positions Bear Oxygen Atoms under Mild Conditions
HELVETICA CHIMICA ACTA, cilt.91, sa.12, ss.2299-2307, 2008 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 91 Sayı: 12
- Basım Tarihi: 2008
- Doi Numarası: 10.1002/hlca.200890250
- Dergi Adı: HELVETICA CHIMICA ACTA
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2299-2307
- Atatürk Üniversitesi Adresli: Evet
Özet
Reductions of compounds whose benzylic positions bear O-atoms, such as benzyl alcohol, dibenzylether, styrene oxide, benzaldehyde, acetophenone, and benzophenone, to the corresponding non-conjugated dienes were performed by using t-BuOH, Li, and gaseous NH(3) in THF at room temperature. In these reductions, it was observed that the functional groups at benzylic positions were reduced firsts.