Synthesis of polypyrrole (PPy) based porous N-doped carbon nanotubes (N-CNTs) as catalyst support for PEM fuel cells

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Öztürk A., Bayrakçeken Yurtcan A.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, cilt.43, sa.40, ss.18559-18571, 2018 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 43 Sayı: 40
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1016/j.ijhydene.2018.05.106
  • Dergi Adı: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.18559-18571
  • Anahtar Kelimeler: Polypyrrole, Carbon nanotubes, FeCl3, Activation, Catalyst support, PEM fuel cell, OXYGEN REDUCTION REACTION, METAL-FREE ELECTROCATALYSTS, MESOPOROUS CARBON, EFFICIENT ELECTROCATALYST, TUBULAR POLYPYRROLE, NITROGEN PRECURSORS, FACILE SYNTHESIS, CO, SUPERCAPACITORS, PERFORMANCE
  • Atatürk Üniversitesi Adresli: Evet

Özet

In this study, it was aimed to synthesize catalytically active, high surface area carbon nanotubes (CNTs) by means of nitrogen doping (N-doping). The synthesized nitrogen doped carbon nanotubes (N-CNTs) were used as Pt catalyst support in order to improve oxygen reduction reaction (ORR) kinetics at the cathode electrode in PEM fuel cell. Polypyrrole (PPy) was served as both carbon and nitrogen source and FeCl3 solution was used as oxidizing agent in the synthesis procedure of N-CNTs. Chemical activation of the materials was made with potassium hydroxide (KOH) solution during 12 and 18 h time periods. It was considered that activation period is of great importance on the properties of the synthesized PPy based N-CNTs. 12 h activated N-CNTs gave higher surface area (1607.2 m(2)/g) and smaller micropore volume (0.355 cm(3)/g) in comparison to 18 h activated N-CNTs having smaller surface area (1170.7 m(2)/g) and higher micropore volume (0.383 cm(3)/g). PEM fuel cell performance results showed that 12 h activated N-CNTs are better catalyst supports than 18 h activated N-CNTs for Pt nanoparticle decoration. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.