High-performance nanocomposite polyvinylpyrrolidone (PVP)-Co@C fibers based heterojunction photodetector


YILDIRIM F., Havigh R. S., Chenari H. M., Nuhzat S., AYDOĞAN Ş.

Journal of Alloys and Compounds, cilt.1057, 2026 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1057
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1016/j.jallcom.2026.186738
  • Dergi Adı: Journal of Alloys and Compounds
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex, INSPEC, Public Affairs Index
  • Anahtar Kelimeler: Electrospun nanofibers, PVP-Co@C Fowler-Nordheim (F-N) tunneling, Heterojunction photodetector
  • Atatürk Üniversitesi Adresli: Evet

Özet

We design and demonstrate a self-powered broadband photodetector based on PVP-Co@C nanofibers/n-Si heterojunction via electrospun of the nanofibers onto n-Si. The composite fiber was characterized in terms of its structural, morphological and chemical, properties by a wide range of analytical techniques such as X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and Fourier-transform infrared spectroscopy (FTIR), respectively. Electrooptical measurements of the heterojunction device were analyzed in UV, Vis and IR region using current-voltage characteristics. Experimental results showed that the PVP-Co@C nanofibers/n-Si heterojunction detector can operate in the UV-Vis-IR region with low power consumption even without the need for an external voltage. The device exhibited outstanding performance at zero bias such that the high on/off ratio of 1.35 × 10⁵ and detectivity of 2.87 × 1011 Jones, respectively for 590 nm illumination. Besides, its UV detectivity and EQE reached as high as 2.72 × 1011 Jones (zero bias) and 516 (%) (at −2.0 V), respectively.