Copolymers of 2-acrylamido-2-methyl-1-propanesulfonic acid/maleic acid: Synthesis, characterization and antimicrobial activity

Soykan C., Coskun R., Delibas A., Sahin E.

CHINESE JOURNAL OF POLYMER SCIENCE, cilt.25, sa.5, ss.491-500, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 25 Sayı: 5
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1142/s0256767907002382
  • Dergi Adı: CHINESE JOURNAL OF POLYMER SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.491-500
  • Anahtar Kelimeler: poly(2-acrylamido-2-methyl-1, propanesulfonic acid-co-maleic acid), Thermogravimetric analysis, SEM analysis, Monomer reactivity ratios, REACTIVITY RATIOS, LINEAR METHODS
  • Atatürk Üniversitesi Adresli: Evet

Özet

2-Acrylamido-2-methyl-1-propanesulfonic acid (AMPS), and maleic acid (MA) copolymerized with different feed ratios using N,N-dimethylformamide as a solvent and benzoyl peroxide (Bz(2)O(2)) as an initiator at 70 degrees C. Structure and composition of copolymers for a wide range of monomer feed were determined by elemental analysis ( content of N for AMPS-units). Monomer reactivity ratios for AMPS (M-1)-MA (M-2) pair were determined by the application of conventional linearization methods such as Fineman-Ross (F-R), Kelen-Tuedoes (KT) and Extended Kelen-Tuedoes (EKT) and a nonlinear error invariable model method using a computer program RREVM. The characterizations were done by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) thermal gravimetry analysis (TGA), and and X-ray diffraction. The antimicrobial effects of polymers were also tested on various bacteria, and yeast.