Photoswitching in Two-Component Surface-Mounted Metal-Organic Frameworks: Optically Triggered Release from a Molecular Container
ACS NANO, cilt.8, sa.2, ss.1463-1467, 2014 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 8 Sayı: 2
- Basım Tarihi: 2014
- Doi Numarası: 10.1021/nn405469g
- Dergi Adı: ACS NANO
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1463-1467
- Anahtar Kelimeler: thin films, metal-organic frameworks, photoswitching, molecular release, azobenzene, THIN-FILMS, GROWTH, ADSORPTION, ROUTE, MOF
- Atatürk Üniversitesi Adresli: Evet
Özet
The remote control of surface properties is one of the key challenges in interfacial systems chemistry. Here, we report the realization of a SURMOF (surface-mounted metal-organic framework)-based hybrid system in which a crucial component can be switched by light. The realization of this two-component system is made possible by installing vertical compositional gradients via liquid-phase epitaxy. After loading the porous coating with guest molecules, its release is initiated by illumination with visible light and monitored by a quartz crystal microbalance.