Preparation of arylmagnesium/lithium from aryl bromides and their coupling and substitution reactions in tetrahydrofuran

Gundogdu O., ALTUNDAŞ R., KARA Y.

APPLIED ORGANOMETALLIC CHEMISTRY, cilt.31, sa.10, 2017 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 31 Sayı: 10
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1002/aoc.3719
  • Dergi Adı: APPLIED ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Atatürk Üniversitesi Adresli: Evet

Özet

One-pot synthesis of 2-aryltetrahydrofurans was achieved by a coupling reaction between arylmagnesium bromides prepared in situ and tetrahydrofuran under mild conditions. The reaction between ArBr and n-BuLi gave unexpected butylbenzene derivatives in moderate yields.