Effect of some pre-treatments on the adsorption of methylene blue by Balkaya lignite

Karaca S., Gurses A., Bayrak R.

ENERGY CONVERSION AND MANAGEMENT, cilt.45, ss.1693-1704, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 45
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1016/j.enconman.2003.09.026
  • Dergi Adı: ENERGY CONVERSION AND MANAGEMENT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1693-1704
  • Anahtar Kelimeler: adsorption, demineralization, pyrolysis, HCl treatment, lignite, AQUEOUS-SOLUTION, COAL, PYROLYSIS
  • Atatürk Üniversitesi Adresli: Evet

Özet

In this study, the effects of some pre-treatments, such as HCl treatment, demineralization and pyrolysis, under a CO2 atmosphere at different temperatures on the adsorption of methylene blue by Balkaya lignite were investigated. The adsorption capacities of the samples were determined before and after these pre-treatments. In addition, the removals of pyritic and organic sulfur and ash contents for the same coal samples were also defined. It was found that the adsorption capacities of the samples decreased after these pre-treatments. The decrease in adsorption capacity with pyrolysis can be attributed to the changes in surface morphology and/or pore size distribution of the coal samples. On the other hand, the observed decrease in adsorption capacity with removal of carbonates and silicates shows that these minerals have an important effect on methylene blue adsorption, and the adsorption considerably occurs through electrostatic interactions. In addition, the obtained results showed that the organic sulfur presence in the coal matrix have a positive effect on the methylene blue adsorption. (C) 2003 Elsevier Ltd. All rights reserved.