Boron removal from aqueous solutions by activated carbon impregnated with salicylic acid

ÇELİK Z., CAN B., Kocakerim M. M.

JOURNAL OF HAZARDOUS MATERIALS, cilt.152, sa.1, ss.415-422, 2008 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 152 Sayı: 1
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.jhazmat.2007.06.120
  • Dergi Adı: JOURNAL OF HAZARDOUS MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.415-422
  • Anahtar Kelimeler: activated carbon, adsorption, boron, impregnation, salicylic acid, BORIC-ACID, ION-EXCHANGE, CONTAINING WASTEWATERS, ADSORPTION, EXTRACTION, BATCH, 1,3-DIOLS, PH
  • Atatürk Üniversitesi Adresli: Evet

Özet

In this study, the removal of boric acid from aqueous solution by activated carbon impregnated with salicylic acid was studied in batch system. pH, adsorbent amount, initial boron concentration, temperature, shaking rate and salicylic acid film thickness were chosen as parameters. Boron removal efficiencies increased with increasing adsorbent amount, temperature and pH, decreasing initial boron concentration. As thickness of salicylic acid film on activated carbon becomes thin up to 0.088 nm, the efficiency increased, and then, the efficiency decreased with becoming thinner than 0.088 nm of salicylic acid film. Shaking rate was no effect on removal efficiency. In result, it was determined that the use of salicylic acid as an impregnant for activated carbon led to the increase of the amount of boron adsorbed. A lactone ring, being the most appropriate conformation, forms between boric acid and -COOH and -OH groups of salicylic acid. (c) 2007 Elsevier B.V. All rights reserved.