Facilitation of water management in low Pt loaded PEM fuel cell by creating hydrophobic microporous layer with PTFE, FEP and PDMS polymers: Effect of polymer and carbon amounts

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Öztürk A., Fıçıcılar B., Eroğlu İ., Bayrakçeken Yurtcan A.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, cilt.42, sa.33, ss.21226-21249, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 42 Sayı: 33
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1016/j.ijhydene.2017.06.202
  • Dergi Adı: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.21226-21249
  • Anahtar Kelimeler: Polydimethylsiloxane, Hydrophobic material, Microporous layer, Water management, PEM fuel cell, GAS-DIFFUSION LAYER, MICRO-POROUS LAYER, ULTRA-LOW, CATALYST LAYER, SUPERHYDROPHOBIC SURFACE, HUMIDITY CONDITIONS, RELATIVE-HUMIDITY, CATHODE CATALYST, MOLECULAR-WEIGHT, MEMBRANE
  • Atatürk Üniversitesi Adresli: Evet

Özet

Microporous layers (MPLs) were prepared with different hydrophobic polymers to establish water management in polymer electrolyte membrane (PEM) fuel cells. Besides conventionally used polymers polytetrafluoroethylene (PTFE) and fluorinated ethylene propylene (FEP), two different molecular weights (MW) of polydimethylsiloxane (PDMS) polymer were used as hydrophobic materials in MPL. Membrane electrode assemblies (MEAs) having MPLs with low MW PDMS polymer exhibited the best fuel cell performance compared to the PTFE and FEP based ones. Thus it is concluded that PDMS polymer has a great potential to be used as hydrophobic material for MPL to reduce flooding phenomena in PEM fuel cell. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.