Substrate-controlled diastereoselective aziridination of alkenes using 3-acetoxyaminoquinazolinone in the presence of hexamethyldisilazane

ULUKANLI, S; KARABUGA, S; CELIK, A; Kazaz, Cavit

doi:10.1016/j.tetlet.2004.11.080

Substrate-controlled diastereoselective aziridination of alkenes using 3-acetoxyaminoquinazolinone in the presence of hexamethyldisilazane

ULUKANLI S., KARABUGA S., CELIK A., Kazaz C.

TETRAHEDRON LETTERS, cilt.46, sa.2, ss.197-199, 2005 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 46 Sayı: 2
Basım Tarihi: 2005
Doi Numarası: 10.1016/j.tetlet.2004.11.080
Dergi Adı: TETRAHEDRON LETTERS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.197-199
Anahtar Kelimeler: aziridination, 3-acetoxyaminoquinazolinone, 8-phenylmenthol, substrate-controlled diastereoselective aziridination, ASYMMETRIC INDUCTION, AGENTS
Atatürk Üniversitesi Adresli: Evet

Özet

8-Phentylmenthol derived alpha,beta-unsaturated esters were aziridinated highly diastereoselectively using 3-acetoxyamino-2-ethylquinazolinone. The yields of these aziridines never greatly improved in the presence of hexamiethyldisilazane. (C) 2004 Elsevier Ltd. All rights reserved.