2-Hydroxyimino-1-phenylethanone thiosemicarbazone monohydrate

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Atıf İçin Kopyala

SARIKAVAKLI N., Babahan I., ŞAHİN E., HÖKELEK T.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.64, 2008 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 64
• Basım Tarihi: 2008
• Doi Numarası: 10.1107/s1600536808004947
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Emerging Sources Citation Index (ESCI), Scopus
• Atatürk Üniversitesi Adresli: Evet

Özet

In the title thiosemicarbazone derivative, C9H10N4OS center dot H2O, intramolecular N-H center dot center dot center dot N hydrogen bonds result in the formation of two nearly coplanar five- and six-membered rings, which are also almost coplanar with the adjacent phenyl ring. The oxime group has an E configuration and is involved in intermolecular O-H center dot center dot center dot O hydrogen bonding as a donor. In the crystal structure, intramolecular O-H center dot center dot center dot S and N-H center dot center dot center dot N and intermolecular O-H center dot center dot center dot O and N-H center dot center dot center dot S hydrogen bonds generate edge-fused R-2(2)(8) and R-4(1)(11) ring motifs. The hydrogen-bonded motifs are linked to each other to form a three-dimensional supramolecular network.