Novel pyrene-BODIPY dyes based on cyclotriphosphazene scaffolds: Synthesis, photophysical and spectroelectrochemical properties
INORGANICA CHIMICA ACTA, cilt.494, ss.132-140, 2019 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 494
- Basım Tarihi: 2019
- Doi Numarası: 10.1016/j.ica.2019.05.022
- Dergi Adı: INORGANICA CHIMICA ACTA
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.132-140
- Atatürk Üniversitesi Adresli: Hayır
Özet
Two novel cyclotriphosphazene compounds (Cpz-2, 3) bearing mono- and distyryl(pyrene) borondipyrromethene (BODIPY) dyes (Bod-4, 5) were synthesized and characterized by using elemental analysis, FT-IR, MALDI-TOF, H-1 NMR, C-13 NMR and (3)1P NMR techniques. The photophysical properties of these novel compounds were investigated by UV-Vis, fluorescence spectroscopy, and electrochemical properties were investigated by CV and SWV measurements. Subsequently, electrochromic properties of novel cyclotriphosphazene compounds (Cpz-2, 3) and their precursor dyes (Bod-4, 5) were investigated via in-situ spectroelectrochemical measurements. According to results, they gave electrochemically manufactured types having various colors in their diverse oxidation states in solution, suggesting that they may have a significant role in development of the color exchange matter in electrochromic device technologies.