Optimizing the structural and photocatalytic performance of Ag-decorated ZnO/Zn(OH)<sub>2</sub> nanoparticles for RhB degradation


ERDOĞAN E., EDEN Ç., CANPOLAT N., ÇIRAK Ç., YILMAZ M.

INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, vol.21, no.3, pp.2010-2023, 2024 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 21 Issue: 3
  • Publication Date: 2024
  • Doi Number: 10.1111/ijac.14675
  • Journal Name: INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, Chemical Abstracts Core, Communication Abstracts, Compendex, INSPEC, Metadex, Civil Engineering Abstracts
  • Page Numbers: pp.2010-2023
  • Keywords: photo-catalysis, RhB, traditional ceramics, Zn(OH)2, ZnO
  • Ataturk University Affiliated: Yes

Abstract

In this study, as-prepared and Ag-decorated ZnO/Zn(OH)(2) composite nanoparticles (NPs) were obtained using the sol-gel technique. First, the effect of aging on the structural, optical, and morphological features was examined. Ag NPs can interact with the electronic structure of ZnO/Zn(OH)(2) NPs, resulting in changes in their energy levels. It was found that the composite NPs obtained after 6 h solution aging increased in full width at half maximum and good crystallinity of the structures from the X-ray diffraction (XRD) measurements. The Raman spectrum supports the experimental data obtained from XRD and Fourier transform infrared, a material containing a mixture of ZnO and Zn(OH)(2). From the morphological study, Ag NPs were successfully decorated on the ZnO/Zn(OH)(2) surface, and composite NPs did not change the morphological appearance of the structure. Second, the photocatalytic performance of the samples was investigated. In the experimental setting, ultra-violet A light was employed as the irradiation source, whereas rhodamine B (RhB) was used as the dyestuff. The photo-degradation of the RhB dyestuff on composite NPs was observed to be 98.5% and 92.5% for 6 and 2 h aged samples, respectively. On Ag NPs, the catalytic performance of the sample was increased up to 95% after 180 min.