Triazine containing N-rich microporous organic polymers for CO2 capture and unprecedented CO2/N2 selectivity
Journal of Solid State Chemistry, cilt.247, ss.113-119, 2017 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 247
- Basım Tarihi: 2017
- Doi Numarası: 10.1016/j.jssc.2017.01.001
- Dergi Adı: Journal of Solid State Chemistry
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.113-119
- Anahtar Kelimeler: CO2 capture, CO2/N-2 selectivity, Porous organic polymers, N-rich frameworks
- Atatürk Üniversitesi Adresli: Hayır
Özet
Targeted synthesis of microporous adsorbents for CO2 capture and storage is very challenging in the context of remediation from green house gases. Herein we report two novel N-rich microporous networks SB-TRZ-CRZ and SB-TRZ-TPA by extensive incorporation of triazine containing tripodal moiety in the porous polymer framework. These materials showed excellent CO2 storage capacities: SB-TRZ-CRZ displayed the CO2 uptake capacity of 25.5 wt% upto 1 bar at 273 K and SB-TRZ-TPA gave that of 16 wt% under identical conditions. The substantial dipole quadruple interaction between network (polar triazine) and CO2 boosts the selectivity for CO2/N2. SB-TRZ-CRZ has this CO2/N2 selectivity ratio of 377, whereas for SB-TRZ-TPA it was 97. Compared to other porous polymers, these materials are very cost effective, scalable and very promising material for clean energy application and environmental issues.