STEREOSPECIFIC SYNTHESIS OF CONDURAMINE-F4 AND CONDURITOL-F (LEUCANTHEMITOL)

SECEN H., GULTEKIN S., SUTBEYAZ Y., BALCI M.

SYNTHETIC COMMUNICATIONS, cilt.24, sa.15, ss.2103-2108, 1994 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 24 Sayı: 15
  • Basım Tarihi: 1994
  • Doi Numarası: 10.1080/00397919408010222
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2103-2108
  • Atatürk Üniversitesi Adresli: Evet

Özet

Stereospecific synthesis of Conduramine-F4 and Conduritol-F has been achieved by fully stereospecific cyloaddition of singlet oxygen to cyclohexadiene ketal 1 followed by reductive extrusion of one oxygen atom. The obtained monoepoxide 3 has been smoothly opened to conduritol-F4 and conduramine-F4 6 by water and ammonia, respectively.