Chemical shifts in the Kα1,2 and Kβ1,3 X-ray emission spectra for halogen compounds of elements with atomic numbers ranging from 22 to 29 were measured using a wavelength-dispersive X-ray fluorescence spectrometer

BOYDAŞ, Elif

doi:10.1016/j.physo.2025.100316

Chemical shifts in the Kα1,2 and Kβ1,3 X-ray emission spectra for halogen compounds of elements with atomic numbers ranging from 22 to 29 were measured using a wavelength-dispersive X-ray fluorescence spectrometer

BOYDAŞ E.

Physics Open, cilt.26, 2026 (ESCI, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 26
Basım Tarihi: 2026
Doi Numarası: 10.1016/j.physo.2025.100316
Dergi Adı: Physics Open
Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
Anahtar Kelimeler: Chemical shifts, Halogens compounds, Ligand atom, WDXRF
Atatürk Üniversitesi Adresli: Evet

Özet

This study aimed to investigate the chemical shifts and full widths at half maximum (FWHM) of the Kα1,2 and Kβ1,3 X-ray emission lines in selected halogen compounds of elements with atomic numbers ranging from 22 to 29. A Wavelength-Dispersive X-ray Fluorescence (WDXRF) spectrometer was employed for this analysis. The FWHM differences (ΔFWHM) of these emission lines were calculated by using the corresponding metallic element as a reference. The data revealed a clear pattern, showing larger chemical shifts for fluorine-containing compounds compared to chlorine-containing ones. In addition, the Kβ1,3 lines generally show larger chemical shifts and wider full widths at half maximum (FWHM) compared to the Kα lines. The chemical shift also tends to increase as the number of coordinating ligand atoms rises.