Spectroscopic, thermal and voltammetric studies of crystalline complex trans-N,N '-bis(salicylidene)-1 ',2 '-cyclohexanediamine with Cu(II)

ASLANTAŞ, MEHMET; TÜMER, MEHMET; ŞAHİN, Ertan

doi:10.1016/j.saa.2007.12.015

Spectroscopic, thermal and voltammetric studies of crystalline complex trans-N,N '-bis(salicylidene)-1 ',2 '-cyclohexanediamine with Cu(II)

Atıf İçin Kopyala

ASLANTAŞ M., TÜMER M., ŞAHİN E.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.71, sa.1, ss.263-268, 2008 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 71 Sayı: 1
Basım Tarihi: 2008
Doi Numarası: 10.1016/j.saa.2007.12.015
Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.263-268
Atatürk Üniversitesi Adresli: Evet

Özet

The dimeric complex, [C20H2OCuN2O2](2). has been prepared and characterized by thermal analysis, IR spectroscopy and single-crystal X-ray diffraction techniques. The Cu atom in the binuclear complex exists in a distorted square-pyramidal configuration, defined by three O atoms and two N atoms. The crystal structure is stabilized by intermolecular C-H center dot center dot center dot O hydrogen bonding interaction. The electrochemical property of the complex was investigated in CH2Cl2 by cyclic voltarnmetry at 100 mV s(-1) scan rate. (C) 2007 Elsevier B.V. All rights reserved.