Synthesis and Catalytic Asymmetric Applications of Quinazolinol Ligands

Karakaya I., KARABUĞA Ş., Mart M., ALTUNDAŞ R., ULUKANLI S.

SYNTHESIS-STUTTGART, cilt.48, sa.11, ss.1719-1726, 2016 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 48 Sayı: 11
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1055/s-0035-1561584
  • Dergi Adı: SYNTHESIS-STUTTGART
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1719-1726
  • Atatürk Üniversitesi Adresli: Evet

Özet

A range of chiral quinazolinol ligands were efficiently synthesized and subsequently investigated for catalytic chiral induction in both the asymmetric phenylation of aryl aldehydes and the asymmetric epoxidation of chalcones. Encouragingly, high enantioselectivities (up to 95%) and yields (up to 98%) were achieved under the optimized reaction conditions.