One-pothomo- andcross-couplingof diazanaphthalenes viaC-Hsubstitution: Synthesis of Bis- andTris-diazanaphthalenes

UÇAR S., DAŞTAN A.

JOURNAL OF HETEROCYCLIC CHEMISTRY, cilt.57, sa.11, ss.4013-4022, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 57 Sayı: 11
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1002/jhet.4111
  • Dergi Adı: JOURNAL OF HETEROCYCLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aquatic Science & Fisheries Abstracts (ASFA), Chimica, EMBASE
  • Sayfa Sayıları: ss.4013-4022
  • Atatürk Üniversitesi Adresli: Evet

Özet

The transition metal-free coupling reactions of unactivated diazanaphthalenes were studied using only lithium tetramethylpiperidine (LiTMP) reagent. Symmetrical and nonsymmetrical bis-diazanaphthalenes were synthesized in moderate to high yield by homo- and cross-coupling of related monomers. In addition, the single-step synthesis of diquinoxalino [2,3-a: 2', 3'c] phenazine and 2,2': 3', 2 '' - terquinoxaline using the appropriate equivalent amount of LiTMP was performed. The products were characterized by means of NMR spectroscopy and HRMS spectrometry.