Direct synthesis of trans-1,4-diacetoxycyclohexa-2,5-diene by electrochemical reduction of r-1,t-4-diacetoxy-t-2,c-3-dibromocyclohex-5-ene

KELEBEKLI L., Demir U., KARA Y.

JOURNAL OF CHEMICAL RESEARCH, sa.11, ss.402-403, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1039/a702167d
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Metadex
  • Sayfa Sayıları: ss.402-403
  • Atatürk Üniversitesi Adresli: Evet

Özet

Electrochemical reduction of r-1,t-4-diacetoxy-t-2,c-3-dibromocyclohex-5-ene 1 gives only trans-1,4-diacetoxycyclohexa-2,5-diene 2 in good yield while the commonly used Zn reduction gives a product mixture containing 2 and acetoxybenzene 3 derived from acetoxy elimination.