Modular Synthesis of Planar-Chiral para-Substituted Paracyclophanes by Double Suzuki Coupling
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, sa.31, ss.6132-6135, 2012 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Basım Tarihi: 2012
- Doi Numarası: 10.1002/ejoc.201201043
- Dergi Adı: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.6132-6135
- Anahtar Kelimeler: Cyclophanes, Cross-coupling, Chirality, Boron, Hydrocarbons, MACRO RINGS, DERIVATIVES
- Atatürk Üniversitesi Adresli: Evet
Özet
The first synthesis of enantiomerically pure 4,7-paracyclophane ditriflate starting from a quinone was reported. Using this molecule, mono- or dicoupling with boronic acids delivered enantiomerically pure arylparacyclophanes.