Modular Synthesis of Planar-Chiral para-Substituted Paracyclophanes by Double Suzuki Coupling

Cakici M., BRAESE S.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, sa.31, ss.6132-6135, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1002/ejoc.201201043
  • Dergi Adı: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.6132-6135
  • Anahtar Kelimeler: Cyclophanes, Cross-coupling, Chirality, Boron, Hydrocarbons, MACRO RINGS, DERIVATIVES
  • Atatürk Üniversitesi Adresli: Evet

Özet

The first synthesis of enantiomerically pure 4,7-paracyclophane ditriflate starting from a quinone was reported. Using this molecule, mono- or dicoupling with boronic acids delivered enantiomerically pure arylparacyclophanes.