Synthesis and Diels-Alder cycloaddition reaction of norbornadiene and benzonorbornadiene dimers

NİŞANCI B., DALKILIC E., GUNEY M., DAŞTAN A.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, cilt.5, 2009 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 5
  • Basım Tarihi: 2009
  • Doi Numarası: 10.3762/bjoc.5.39
  • Dergi Adı: BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Anahtar Kelimeler: benzonorbornadiene, Diels-Alder reaction, norbornadiene, Stille coupling, HIGH-TEMPERATURE BROMINATION, DERIVATIVES, DIENES
  • Atatürk Üniversitesi Adresli: Evet

Özet

Dimeric forms of norbornadiene and benzonorbornadiene were synthesized starting with known monobromide derivatives. The Diels-Alder cycloaddition reaction of dimers with TCNE and PTAD was investigated and new norbornenoid polycyclics were obtained. All compounds were characterized properly using NMR spectroscopy.