Bromination of tricyclo[7.2.1.0(2,7)]dodeca-2,4,6,10-tetraene derivatives: Electronic and neighboring group effects on bromination

Dastan A.

TURKISH JOURNAL OF CHEMISTRY, cilt.28, sa.6, ss.715-724, 2004 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 28 Sayı: 6
  • Basım Tarihi: 2004
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.715-724
  • Atatürk Üniversitesi Adresli: Evet

Özet

The bromination reaction of tricyclo[7.2. 1.0(2.7))dodeca-2,4,6,10-tetraene derivatives was studied. The bromination of 9 gave only rearranged products 12 and 13, while the bromination of 8 with molecular bromine formed both rearranged 12 and non-rearranged products 15 and 16. The possible role of a substituent in the rearrangements was examined. All compounds were characterized property in particular by NMR spectra and chemical transformation.