Study on Crystallization of PVC/Graphene/Seashell Hybrid Biocomposites by Thermal and Hardness Analysis


MİNDİVAN F., GÖKTAŞ M., BAYRAKÇEKEN H.

Iranian Journal of Materials Science and Engineering, cilt.21, sa.4, ss.91-102, 2024 (ESCI) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 21 Sayı: 4
  • Basım Tarihi: 2024
  • Doi Numarası: 10.22068/ijmse.3676
  • Dergi Adı: Iranian Journal of Materials Science and Engineering
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus, Directory of Open Access Journals
  • Sayfa Sayıları: ss.91-102
  • Anahtar Kelimeler: Crystallinity, Graphene, PVC Hybrid biocomposite, Seashell, Thermal Analysis
  • Atatürk Üniversitesi Adresli: Evet

Özet

Natural-reinforced hybrid composites, called "eco-materials,"are increasingly important for protecting the environment and eliminating waste problems. In this study, hybrid biocomposites were produced by the colloidal mixing method using seashell (SS) as natural waste, two graphene derivatives (graphene oxide (GO) and reduced graphene oxide (RGO)) as filler material, and polyvinyl chloride (PVC) as the polymer matrix. The crystallization and mechanical properties of hybrid biocomposites were examined based on their thermal properties using TGA and DSC analysis. Compared to PVC/GO and PVC/RGO composites with identical weight percentages of GO and RGO, the PVC/GO composite exhibited superior thermal stability and crystallinity, resulting in elevated hardness values for the same composite. These results were attributed to the better interaction of GO with PVC due to the higher number of oxygen-containing functional groups in GO than in RGO. However, the PVC/RGO/SS hybrid biocomposites exhibited superior properties than PVC/GO/SS hybrid biocomposites. The greatest crystallinity values were 39.40% for PVC/RGO/SS-20 compared to PVC/RGO composite and 29.21% for PVC/GO/SS-20 compared to PVC/GO. The PVC/RGO/SS-20 hybrid biocomposite showed the greatest gain in hardness value, up 18.47% compared to the PVC/RGO composite. No significant change was observed in the melting and weight loss temperatures as the SS content increased; however, the crystallinity and glass transition temperatures in hybrid biocomposites increased as the SS content increased. All analysis results demonstrated the achievement of SS-graphene-PVC interactions, suggesting that SS waste could enhance the thermal and mechanical properties of biocomposite production.