А kinеtiс аnаlysis fоr prоduсtiоn of саlсium bоrоgluсоnаtе frоm colemanite

Demir F., Al-Ani A. O. A., Laçin Ö.

International Journal of Chemical Kinetics, cilt.52, sa.11, ss.769-776, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 52 Sayı: 11
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1002/kin.21398
  • Dergi Adı: International Journal of Chemical Kinetics
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Applied Science & Technology Source, Chimica, Compendex
  • Sayfa Sayıları: ss.769-776
  • Anahtar Kelimeler: colemanite, dissolution kinetics, gluconic acid, solid-liquid reaction, calcium borogluconate, DISSOLUTION KINETICS, GLUCONIC ACID, ULEXITE
  • Atatürk Üniversitesi Adresli: Evet

Özet

In this paper, the kinetic model of colemanite dissolution in gluconic acid solutions was carried out in a batch reactor. The effects of the particle size, reaction temperature, stirring speed, gluconic acid concentration, and solid/liquid ratio on colemanite dissolution were experimentally studied. The empirical parameters were the gluconic acid concentration (0.05-0.2 M), the temperature (20-50 degrees C), the solid/liquid ratio (0.05/500-1.5/500 g.L-1), particle size (193.5-1000 mu m), and stirring speed (400-700 rpm). The kinetic models for heterogeneous solid-liquid reactions were used with the dissolution data in evaluating the kinetic. The dissolution of colemanite in gluconic acid solutions was controlled by diffusion through the product layer. The activation energy was found to be 8.39 kJ.mol(-1). The rate expression associated with the dissolution rate of colemanite depending on the parameters chosen may be summarized as follows: 1-3(1-X)2/3+2(1-X)=1.2e-8.39/RTt.