Synthesis, characterization, and application to transfer hydrogenation of eta(6)-(3,4,5-trimethoxybenzyl)-eta(1)-N-heterocyclic carbene-ruthenium complex

Demir, Serpil; ÖZDEMİR, İSMAİL; Cetinkaya, Bekir; ŞAHİN, Ertan; Arici, Cengiz

doi:10.1080/00958972.2011.589510

Synthesis, characterization, and application to transfer hydrogenation of eta(6)-(3,4,5-trimethoxybenzyl)-eta(1)-N-heterocyclic carbene-ruthenium complex

Demir S., ÖZDEMİR İ., Cetinkaya B., ŞAHİN E., Arici C.

JOURNAL OF COORDINATION CHEMISTRY, cilt.64, sa.14, ss.2565-2572, 2011 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 64 Sayı: 14
Basım Tarihi: 2011
Doi Numarası: 10.1080/00958972.2011.589510
Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.2565-2572
Atatürk Üniversitesi Adresli: Evet

Özet

A new chelating ruthenium complex was synthesized using an electron-rich olefin and [RuCl2(p-cymene)](2) and characterized structurally and spectroscopically. The structure of the complex was verified using X-ray crystallography. The complex displayed high activities in transfer hydrogenation.