A novel synthesis of DL-proto-, and DL-vibo-quercitol via 1,4-cyclohexadiene

Salamci E., Secen H., SUTBEYAZ Y., BALCI M.

SYNTHETIC COMMUNICATIONS, cilt.27, sa.13, ss.2223-2234, 1997 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 13
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1080/00397919708003375
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2223-2234
  • Atatürk Üniversitesi Adresli: Evet

Özet

Photooxygenation of 1,4-cyclohexadiene 3 followed by reduction with LiAlH4 or thiourea gave (25/1)-cyclohex-3-ene-triol 7a. trans-Hydroxylation of triol 7a with three different methods afforded both of proto-quercitol la and vibo-quercitol 2a.