Comparative transfer hydrogenation performance of homogeneous and heterogeneous ruthenium (II) catalysts derived from a Schiff base ligand

Ispir E., ŞAHİN E., Ikiz M., Aktas A.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.830, ss.188-195, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 830
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1016/j.jorganchem.2016.12.027
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.188-195
  • Anahtar Kelimeler: Ru(II) complex, Schiff base, Transfer hydrogenation, Heterogeneous catalyst, HIGHLY EFFICIENT, COMPLEXES, KETONES, NANOPARTICLES, REDUCTION, RHODIUM
  • Atatürk Üniversitesi Adresli: Evet

Özet

A new Schiff base ligand (E)-4-(((pyridin-2-ylmethylene)amino)methyl)phenol (L1H) 1 was synthesized and grafted to solid support successfully. Mononuclear Ru(II) complex 2, its solid supported analogue 4 and heterogeneous complex 5 were synthesized with [RuCl2(p-cymene)](2) and RuCl2(PPh3)dppb.