Oxidation reaction of 4-allyl-4-hydroperoxy-2-methoxycyclohexa2,5-dienone in the presence of potassium permanganate without a co-oxidant

GÜLTEKİN M. S., GÖKSU H.

ORGANIC COMMUNICATIONS, cilt.9, sa.4, ss.102-107, 2016 (ESCI) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 9 Sayı: 4
  • Basım Tarihi: 2016
  • Dergi Adı: ORGANIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.102-107
  • Atatürk Üniversitesi Adresli: Evet

Özet

4-Allyl-4-hydroperoxy-2-methoxycyclohexa-2,5-dienone (5) was synthesized by photooxygenation of commercially available Eugenol in the presence of tetraphenylporphyrin (TPP) as a singlet oxygen sensitizer. The brief and one-pot syntheses of some natural product skeletons were conducted using the corresponding allylic hydroperoxide at different temperatures (0 degrees C and room temperature) with potassium permanganate (KMnO4) in mild condition at N-2(g) atm.